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UV rays break down Collagen and Elastinthe proteins responsible for skins firmness and elasticity

Having worked in the food industry I know that there is no set method of determining shelf life and it is up to the producer to chose what "use by" or "best before" dates they want to put on their stock, based on their own view of the product under normal conditions

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10.2147/DDDT.S82030 47 IlicS.BrcicI.MesterM.FilipovicM.SeverM.KlicekR.et al (2009)

Sigma-Aldrich, 2023b) Its important to note that the specific storage requirements for solution peptides may depend on the peptide sequence and solvent system used