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The first reaction in glutathione synthesis is the ligation of glutamate and cysteine catalyzed by glutamate-cysteine ligase (GCL)

Each type has a unique amino acid profile and micronutrient set

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[33] Although the enzyme is functionally limited to the conversion of superoxide radicals into less toxic oxygen-containing molecules, methodological approaches utilizing phylogenetic and structural protein analysis suggest that three SOD isoforms have evolved independently to combat superoxide accumulation

Rose SR, Lustig RH , Pitukcheewanont P, Broome DC, Burghen GA, Li H, Hudson MM, Kun LE, Heideman RL